There are signals for the Polycom Viewstation at
[Link: ir.premisesystems.com]You should be able to copy those and paste them into ProntoEditNG.
I've never seen that protocol before, so I can't tell exactly how the command numbers (0x0E and 0x0D in your examples) are encoded in the timing data (the long strings of Pronto Hex that you learned and that you can copy from the above URL). It is normal that the Pronto Hex is much longer than the command number it encodes and doesn't directly contal that command number.
I don't see anything about these signals that would make them harder to learn than typical IR signals. Are you trying to learn with the TSU3000 stand-alone, or while it's connected to your PC? That may make a big difference, though in theory learning should be possible either way.
Does the document from the manufacturer give any more detail about the structure of the signals? I'd like to add this protocol to my decoding software. I might be able to guess the structure from the samples at premise, but the manufacturer's document would make that easier. Can you email a copy to me?